PHOSPHATES
Phosphates have wide application in the meat processing industry. They include sodium tripolyphosphate, tetrasodium pyrophosphate, sodium hexametaphosphate, sodium acid pyrophosphate, dissodium phosphate etc..
Alkaline phosphate salts (sodium tripolyphosphate and tetrasodium pyrophosphate) elevate the pH of meat, thus improving its water-holding power. The acid reacting phosphates (alkali-metal salts or ortophosphoric acid and pyrophosphoric acid), on the contrary, lower the pH.
Polyphosphates act as buffers; they sequester cations and raise the ionic strength of the solution. Tetrasodium pyrophosphate interacts directly with actomyosin dissociating it into myosin and actin. Sodium tripolyphosphate has a similar effect, but is active after a short delay for enzymatic hydrolysis to tetrasodium pyrophosphate, while sodium hexametaphosphate does not interact at all. The actin and myosin, dissociated by tetrasodium pyrophosphate and sodium tripolyphosphate, are then solubilized by salt and thereby their water binding capacity is enhanced. During heat coagulation of highly solubilized protein, the water is immobilized in the pores of formed gel structure.
Although both sodium tripolyphosphate and tetrasodium pyrophosphate are superior to all other phosphates, sodium tripolyphosphates have a higher solubility and are less prone to form insoluble precipitates. Sodium acid pyrophosphate in particular is often utilized in sausages. The permissible maximum concentration of residual phosphates in meat products is set at 0.5 percent.
Phosphates retard development of oxidative rancidity in meat products.